𝔖 Bobbio Scriptorium
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An unusual reductive cyclization

✍ Scribed by R. Kannan; P. Geetha; S. Swaminathan

Book ID
104241274
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
199 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Li-h.? reduction of 14-Ethynyl-lfi -hydroxy-6,oxo-Sa-methyl-1,2,3,4, 6,7,8,8a octah J ronaphthalene 5 furnishes, in addition to reported products, the tricyclic compound 8.

Metal_ammonia reductions of the ketones 1 and 3 under controlled conditions are knownl to give the cyclopropanes 2 2nd 4 fespectively.

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