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An unusual reaction of trichloromethane with acylals in the interphase catalysis conditions.

✍ Scribed by G.V. Kryshtal; V.S. Bogdanov; L.A. Yanovskaya; Yu.P. Volkov; E.I. Trusova

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
227 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

Summarv Aldehyde diacetates react with trichloromethane in the standard interphase'catalysis conditions to form d-trichloromethylcarbinols or their acetates depending on temperature and time of the reaction.

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## Abstract magnified image The treatment of a 1,2,5‐thiadiazolidine 1,1‐dioxide‐derived phenylthiomethyl ether with sulfuryl chloride yielded an unexpected dimeric product whose structure was determined using X‐ray crystallography. A plausible mechanism for the formation of this product is propos