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Formation of an unusual product in the reaction of a 1,2,5-thiadiazolidine 1,1-dioxide-derived thioether with sulfuryl chloride

✍ Scribed by Dengfeng Dou; Erach R. Talaty; Curtis E. Moore; John C. Bullinger; David M. Eichhorn; William C. Groutas

Publisher: Journal of Heterocyclic Chemistry
Year: 2009
Tongue: English
Weight: 284 KB
Volume: 46
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.136

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✦ Synopsis

Abstract

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The treatment of a 1,2,5‐thiadiazolidine 1,1‐dioxide‐derived phenylthiomethyl ether with sulfuryl chloride yielded an unexpected dimeric product whose structure was determined using X‐ray crystallography. A plausible mechanism for the formation of this product is proposed. J. Heterocyclic Chem. (2009).

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