An unusual reaction of flavan-3-ols with acetone of relevance to the formation of the tetracyclic ring system in peltogynoids
✍ Scribed by Jan H. Van Der westhuizen; Jacobus A. Steenkamp; Daneel Ferreira
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 353 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
✦ Synopsis
are in moist acetone subject to acid-catalyzed incorporation of an 1-mcthylethylidcnc fragment between 3-CH and C-2 (Bring) to give a tetracyclic ring system reminiscent of the peltogynoid series of flavonoids.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract The 4‐substituted 1‐phenyl‐1‐butene‐3‐ynes 1a–c and the 2‐ethynylstyrenes 7a–c were subjected to high‐temperature pyrolysis. The cycloisomerization products isolated suggest that these are formed by three competing processes: by (i) an electrocyclic or a molecule‐induced, (ii) an alkeny