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An Unexpected Reaction of Trimethylsilyl Fluorosulfonyldifluoroacetate (TFDA) with Imidazoles. Formation of N-Difluoromethylthioureas.

✍ Scribed by Wei Xu; Khalil A. Abboud; Ion Ghiviriga; William R. Jr. Dolbier; Magdalena Rapp; Stanislaw F. Wnuk

Book ID
102007440
Publisher
John Wiley and Sons
Year
2007
Weight
19 KB
Volume
38
Category
Article
ISSN
0931-7597

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An unexpected reaction of CF3SCl with n-
An unexpected reaction of CF3SCl with n-pentane
✍ A. Kolasa πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 46 KB

## Studies on the reaction of varioua open-chain and cyclic ethers with trifluoromethylsulphenyl chloride in n-pentane in the prescnce of pyridine showed that the only fluorinated product of these reactions was a mixture of CF3S-substituted n-pentane derivatives.