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Cyanosulfines: An Unexpected Reaction of N,N-bis(trimethylsilyl)ynamines

✍ Scribed by Dipl.-Chem. Thomas Schmid; Prof. Dr. Michael Hanack; Dr. Cäcilia Maichle; Prof. Dr. Joachim Strähle

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
235 KB
Volume
32
Category
Article
ISSN
0044-8249

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The Reaction of Nitramines and Their N-Trimethylsilyl Derivatives with N,N-Bis(trimethylsilyloxy)enamines. -Trimethylsilylated alkylnitramine (I) reacts with N,N-bis(trimethylsilyloxy)aminopropene (II) as N-centered nucleophile to afford selectively the trimethylsilylated oxime (III) which on hydro