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ChemInform Abstract: Reaction of Trimethylsilyl Benzhydryl Ethers with Methyl N-( Trimethylsilyl)pyroglutamate: An Easy and Rapid N-Alkylation.

โœ Scribed by B. RIGO; P. GAUTRET; A. LEGRAND; J.-P. HENICHART; D. COUTRIER

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Reaction of Nitramines and Their N-Trimethylsilyl Derivatives with N,N-Bis(trimethylsilyloxy)enamines.
โœ S. L. IOFFE; L. M. MAKARENKOVA; YU. A. STRELENKO; I. V. BLIZNETS; V. A. TARTAKOV ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

The Reaction of Nitramines and Their N-Trimethylsilyl Derivatives with N,N-Bis(trimethylsilyloxy)enamines. -Trimethylsilylated alkylnitramine (I) reacts with N,N-bis(trimethylsilyloxy)aminopropene (II) as N-centered nucleophile to afford selectively the trimethylsilylated oxime (III) which on hydro