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An improved synthesis of a polymer-supported distannane and its application to radical formation

✍ Scribed by Jörg Junggebauer; Wilhelm P Neumann

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
578 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

A polymer-supported distannane 1 was prepared by treatment of tin halide resin with lithium naphthalenide or sodium naphthalenide in THF. The content of the polymers 1 was determined to be 0.95 to 1.13 mmol/g tin as ditin. The polymer-supported distannane reagent was successfully applied to radical cyclizations of acyclic ct-haloesters to yield 7-butyrolactones.

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