A simple route for the enanrioselective synthesis of key intermediates (11 and 12) for the total synthesis of forskolin has been developed starting from acid 6 and (S)-alcohol 5. The latter is prepared by enantioselective catalytic CBS reduction of dienone 3, and is converted by an intramolecular Di
An improved procedure for the Blaise reaction: a short, practical route to the key intermediates of the saxitoxin synthesis
โ Scribed by Hannick, Steven M.; Kishi, Yoshito
- Book ID
- 115450571
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 465 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
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