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An improved 1,3-diene synthesis from alkyne and ethylene using cross-enyne metathesis

✍ Scribed by Keisuke Tonogaki; Miwako Mori

Book ID
104250639
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
66 KB
Volume
43
Category
Article
ISSN
0040-4039

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Novel 1,3-diene synthesis from alkyne an
Novel 1,3-diene synthesis from alkyne and ethylene by ruthenium-catalyzed enyne metathesis
✍ Atsushi Kinoshita; Norikazu Sakakibara; Miwako Mori πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 795 KB

A novel 1,3-diene synthetic method from alkyne and ethylene was developed using ruthenium-catalyzed enyne metathesis. The reaction procedure is very simple: A CH2CI 2 solution of alkyne was stirred at room temperature under ethylene gas (1 atm.) in the presence of a catalytic amount of ruthenium ben