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An Extension of the Phase Rule for Adsorption under Equilibrium and Non-Equilibrium Conditions

✍ Scribed by Langmuir, Irving


Book ID
118233974
Publisher
American Institute of Physics
Year
1933
Tongue
English
Weight
902 KB
Volume
1
Category
Article
ISSN
0021-9606

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It is shown that the standard rate law for thermal decomposition of diatomic molecules, AB, in mixtures with an inert species, M, breaks down severely under conditions of vibrational disequilibrium, even when the time scales for relaxation and dissociation