✦ LIBER ✦
A generalized rate law for the thermal dissociation of diatomic molecules under non-equilibrium conditions
✍ Scribed by Heshel Teitelbaum
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 256 KB
- Volume
- 154
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
It is shown that the standard rate law for thermal decomposition of diatomic molecules, AB, in mixtures with an inert species, M, breaks down severely under conditions of vibrational disequilibrium, even when the time scales for relaxation and dissociation