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An Experimental Study of the Solvent Effect on Rate and Selectivity in a Concentrated Diels−Alder Reaction

✍ Scribed by Sheehan, Madoc; Sharratt, Paul


Book ID
120204248
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
65 KB
Volume
3
Category
Article
ISSN
1083-6160

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endo-exo Selectivity in Diels-Alder cycloadditions of several o-quinodimethanes (1-4) with acrylonitrile, 2-(5H)-furanone and N-methylmaleimide has been investigated in acetonitrile solution. Transition structures of the cycloaddition of the parent o-QDM (1), (E,E)-1,8-dimethyl-o-QDM (2), isoindene