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A study on the role of solvent in clay-catalysed Diels—Alder reactions

✍ Scribed by Carlos Cativiela; José M. Fraile; José I. García; José A. Mayoral; François Figueras


Publisher
Elsevier Science
Year
1991
Weight
204 KB
Volume
68
Category
Article
ISSN
0304-5102

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The transition states involved in the hetero-Diels-Alder reactions of acrylaldehyde-ethylene and butadiene-formaldehyde systems were characterized using an efficient method of locating a saddle point on the energy surface of two coordinates calculated with MIND0/3 method. It has been shown that para