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An ESR study of the addition of metal atoms to allene: metal-substituted allyl radicals

โœ Scribed by Chenier, J. H. B.; Howard, J. A.; Mile, B.


Book ID
126245676
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
701 KB
Volume
107
Category
Article
ISSN
0002-7863

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Persistent cyclic acyloxy aminoxyl radicals can be obtained by intramolecular trapping of benzoyl radicals by adjacent aromatic nitro groups whereas analogous intermolecular acyloxy adducts decay by N-O cleavage to give C-nitroso compounds and ultimately acyl aminoxyls. Iwamura and Inamoto' were se