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Nonplanar allyl radicals. ESR studies of the addition of sulfur, silicon and tin-centered radicals to allenes

โœ Scribed by William H. Davis Jr.; Jay K. Kochi

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
246 KB
Volume
17
Category
Article
ISSN
0040-4039

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โœ Herbert Rubin; Hanns Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 686 KB

All arrangements and procedures for steady-state and time-resolved ESR were as described in [4]. The radicals Me,C and Me3C02CCH, were generated by photolysis of the corresponding disubstituted ketones. These undergo type-I cleavage from a short-lived triplet state followed by a fast decarbonylation