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An ESR study of decomposition of carbon-bisulfate compounds

✍ Scribed by S. Mrozowski


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
356 KB
Volume
11
Category
Article
ISSN
0008-6223

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The process of driving out of sulfuric acid from a carbon by heating in vacuum was tracked by ESR measurements. There is a sudden dramatic increase in width of the ESR line, followed by a somewhat slower decrease; the tip of the peak coinciding with the beginning of the driving-out process (-200Β°C).

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AMrae&-Electron spin resonance (ESR) data have been obtained for a well-~aphitizi~ and a poorly-graphitizing pitch as a function of heat-reagent time at reaction temperatures between 4W and 490Β°C. Me~uremen~ of ESR spin concentration and linewidth and of atomic C/H ratio have been used to delineate