An ESR investigation of the dynamical behavior of the cyclopentane cation in CF3CCl3
✍ Scribed by L. Sjöqvist; A. Lund; J. Maruani
- Book ID
- 107942366
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 485 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0301-0104
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📜 SIMILAR VOLUMES
Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup
The internal motion of the cyclopentyl radical, trapped in a halocarbon matrix, CF,ClCFCI,, has been studied utilizing electron spin resonance (ESR) spectroscopy. The lineshapes of the ESR spectra corresponding to the radical exhibit an alternating linewidth effect in the temperature range 1 lo-135