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An enzymic synthesis of a sucrose analog: α-d-xylopyranosyl-β-d-fructofuranoside

✍ Scribed by Gad Avigad; David S. Feingold; Shlomo Hestrin


Book ID
115786689
Publisher
Elsevier Science
Year
1956
Weight
409 KB
Volume
20
Category
Article
ISSN
0006-3002

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Condensation of allyl 3,4-di-O-benzyl-beta-D-xylopyranoside with 2-O-acetyl-3,4,6-tri-O-benzyl-alpha-D-galactopyranosyl chloride in dichloromethane in the presence of silver triflate gave allyl 2-O-(2-O-acetyl-3,4-6-tri-O-benzyl-beta-D-galactopyranosyl)-3,4-di-O benzyl-beta-D-xylopyranoside (7, 83%)