Synthesis of 3-deoxy- and 3-deoxy-3-fluorosucrose, and α-d-allopyranosyl β-d-fructofuranoside
✍ Scribed by Thomas P. Binder; John F. Robyt
- Book ID
- 107725581
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 589 KB
- Volume
- 147
- Category
- Article
- ISSN
- 0008-6215
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📜 SIMILAR VOLUMES
Condensation of Z-deoxy-~-ribose with nitromethane gave, after deionization, a syrupy mixture of epimeric l-nitro-1,3-dideoxy-hexitols. Acid hydrolysis under Nef reaction conditions produced a mixture of 3-deoxy-~-glucose and 3-deoxy-m mannose, separable by cellulose chromatography or fractional cry
As part of a study of the effects of sugar analogs on glycoprotein biosynthesis'V2, it was necessary to prepare 3-deoxy-D-ribo-hexose (4) and 3-deoxy-D-arabino-hexose (5). Several satisfactory syntheses of these deoxy sugars have been reported3-7. For example, 3-deoxy-D-Cbo-hexose may be obtained by