An Enantiospecific Synthesis of Jiadifenolide
โ Scribed by Siler, David A.; Mighion, Jeffrey D.; Sorensen, Erik J.
- Book ID
- 121730489
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 647 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0044-8249
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๐ SIMILAR VOLUMES
Efficient ring cleavage of 9,10-dibromocamphor (3) provides a monocyclic hydroxyacid (5) which can serve as an intermediate in a new enantiospecific synthesis of estrone.
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Enantiospecific total synthesis of an indolizidine alkaloid, ipalbidine, was achieved starting from (-)-pyroglutamic acid by employing an intramolecular McMurry coupling reaction with a low-valent titanium, as a key step.