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An Enantiospecific Synthesis of 2-Pupukeanone.

โœ Scribed by A. Srikrishna; P. Ravi Kumar; S. J. Gharpure


Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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ChemInform Abstract: Enantiospecific Tot
โœ A. SRIKRISHNA; T. J. REDDY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 1 views

Enantiospecific Total Synthesis of (+)-2-Pupukeanone. -The first enantiospecific total synthesis of 2-pupukeanone (X) starting from readily available (R)-carvone (I) is described. Key step in the synthetic sequence is the construction of the tricyclic isotwistane carbon framework via 5-exo-trig rad