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An enantioselective total synthesis of (+)-cassiol

✍ Scribed by Osamu Irie; Yoko Fujiwar; Hisao Nemoto; Kozo Shishido

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
234 KB
Volume
37
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

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A synthesis of the antiulcerogenic compound (+)-cassiol 1b has been achieved in 43% yield starting with lactol (S)-2 and sulfone 26. This short and efficient synthesis features the one-pot Julia olefination reaction of the sodium anion of (S)-2 with 26, through the key intermediate (-)-9. This synth