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ChemInform Abstract: An Enantioselective Total Synthesis of (+)-Cassiol.

โœ Scribed by O. IRIE; Y. FUJIWARA; H. NEMOTO; K. SHISHIDO


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Short Enantiosele
โœ S. MAITI; B. ACHARI; A. K. BANERJEE ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

A Short Enantioselective Synthetic Route to (+)-Cassiol. -Cyclohexenone derivative (VI), a key intermediate for the preparation of (+)-cassiol (VII), is synthesized starting from ฮฒ-methylpropionylacetate (I) by condensation with chiral amine (II) followed by asymmetric Michael reaction with acrolei