An enantioselective approach to chiral pseudoguaianolide intermediates
โ Scribed by Peter T. Lansbury; James P. Galbo; James P. Springer
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 228 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The viability of an enantloselectrve route to pseudogualanolrdes has been established
with the construction of hydroazulenone 2, whose absolute configuration parallels that of radiatin.
๐ SIMILAR VOLUMES
We have recently communicated our results on a novel strategy to etficiently and stereoselectively construct the quassinoid framework via a Diene-Transmissive Diels-Alder strategy (Eq l).l Although both the hetero-and intramolecular Diels-Alders proceeded with complete endo-selectivity, the stereoch
The synthesis of perhydroazulenic lactone 8, a potential precursor for several helenanolides is described. Its structure is determined by X-ray diffraction of the corresponding alcohol 2. During the past three years several groups have reported on the synthesis of pseucioguaianolides possessing a B