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An enantio- and stereocontrolled route to epopromycin B via cinchona alkaloid-catalyzed Baylis–Hillman reaction

✍ Scribed by Yoshiharu Iwabuchi; Tatsuya Sugihara; Tomoyuki Esumi; Susumi Hatakeyama

Book ID: 104231724
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 107 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01676-8

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✦ Synopsis

An enantio-and stereocontrolled route to epopromycin B having the epoxy-b-aminoketone pharmacophore is developed based on the cinchona alkaloid-catalyzed Baylis-Hillman reaction of N-Fmoc-leucinal.

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