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An Efficient Synthesis of Polysubstituted 1,3-Enynes from (E)-β-Iodovinyl Sulfones and Terminal Alkynes

✍ Scribed by Xiao-Xia GU; Mei-Hua XIE; Xin-Yang ZHAO; Ying SUN; Wei ZHANG; Fa-Dong XIE; Shao-Wu WANG

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
86 KB
Volume
26
Category
Article
ISSN
0256-7660

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Novel Two-Step Stereoselective Synthesis of (E)-Enamines and 1-Amino-1, 3-dienes from Terminal Alkynes. -The two-step synthesis of (E)-enamines and 1-amino-1,3-dienes is accomplished by regio-and stereoselective Ru-catalyzed addition of acetic acid to alkynes (I). The resulting acetates react with