An Efficient Synthesis of Epoxydiynes and a Key Fragment of Neocarzinostatin Chromophore
β Scribed by Baker, J. R.; Thominet, O.; Britton, H.; Caddick, S.
- Book ID
- 127159385
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 65 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Total Synthesis of (+)-Neocarzinostatin Chromophore. -The optimized route to the desired antibiotic involves an atypical protocol for the introduction of the amino sugar containing an unprotected N-methylamino group and the removal of all silyl protective groups in a single operation after glycosyl
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The sterem&ctive synthesis of a bicyclic ring system related to Neocarzinostatin and Kedarcidin Chromophonzs is described; key steps involve stereoselective conjugate addition of an enediyne to an enone and intramolecular aldol reaction of a cobalt complexed allcynyl aIdehyde. 0 1997 Elsevier Scienc