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An efficient synthesis of 1-cyano-2,3-unsaturated sugars via the reaction of glycals with Et2AlCN

✍ Scribed by David S Grierson; Martine Bonin; Henri-Philippe Husson; Claude Monneret; Jean-Claude Florent

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 123 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91222-5

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✦ Synopsis

The reaction of qlycals la-d with Et2AlCN in benzene at room temperature leads to formation of the correspondinq l-cyano-2,3-unsaturated suqars 2a-d and 3a-d in qood to excellent yields.

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