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An efficient preparation of the optically active γ -hydroxy stannanes using lipase-catalyzed hydrolysis

✍ Scribed by Toshiyuki Itoh; Tadataka Ohta; Mitsue Sano

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
317 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

A perfect optical resolution of 7 -hydroxystannanes was demonstrated by the method of lipase-catalyzed enantioselective hydrolysis of the corresponding racemic acetates using lipase P(Pw sp.).

The utilization of organotin compounds in modern synthesis continues to grow at an impressive rate.') Although some excellent studies on the application of 7 -hydroxystannanes have been reported, 2) they have concentrated on the use of the achiral ones.

For optically active y -hydroxystannanes, there has been no contribution not only for their use but also for the method of their preparation.

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