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A simple method for the preparation of optically active α -hydroxystannanes by the enantioselective hydrolysis using a lipase

✍ Scribed by Toshiyuki Itoh; Tadataka Ohta


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
109 KB
Volume
31
Category
Article
ISSN
0040-4039

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The first synthesis of diazoesters by direct diazotization of amino acid esters was reported by Curtius I,\*) around 1900. Although this method is well suited for the preparation of diazoacetic ester, 3) it is generally inapplicable to the syntheses of a-substituted-a-diazoesters (I),\*) because of