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An efficient one-pot method for the synthesis of mono- and biscyclopentenones via zirconium-catalyzed cycloalumination of cyclic alkynes and diynes

✍ Scribed by Vladimir A. D’yakonov; Regina A. Tuktarova; Usein M. Dzhemilev


Book ID
104098291
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
300 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis


Mono-and bisaluminacyclopentenes obtained via zirconium-catalyzed cycloalumination with Et 3 Al and cyclic alkynes or diynes can be converted into the corresponding mono-and biscyclopentenones by treatment with CO 2 , ClCOOEt, or CO(OEt) 2 in yields of 34À73%.


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