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An Efficient and General Iron-Catalyzed One-Pot Synthesis of Furans via α-Hydroxy Ketones and Activated Alkynes

✍ Scribed by Hua Cao; Haiying Zhan; Jianyong Wu; Haiping Zhong; Yuanguang Lin; Hong Zhang

Book ID
112082822
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
453 KB
Volume
2012
Category
Article
ISSN
1434-193X

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Mono-and bisaluminacyclopentenes obtained via zirconium-catalyzed cycloalumination with Et 3 Al and cyclic alkynes or diynes can be converted into the corresponding mono-and biscyclopentenones by treatment with CO 2 , ClCOOEt, or CO(OEt) 2 in yields of 34À73%.