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An Efficient Enantioselective Synthesis of (—)-Serricorole

✍ Scribed by Wolfgang Oppolzer; Inès Rodriguez

Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
446 KB
Volume
76
Category
Article
ISSN
0018-019X

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✦ Synopsis

The numbering of 1 corresponds to [2] and is used also for all intermediates; systematic names are given in the Exper. Part.

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For the cleavage of cdrboxylates with lithiated alkylsulfones, see [9].

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## Abstract Blastmycinone, a degradation product of the antibiotic antimycin A, was synthesized with a TiCl~4~‐mediated asymmetric aldolization as the key step. Some unexpected yet interesting chemistry was also observed.