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An Efficient Enantioselective Synthesis of Blastmycinone

✍ Scribed by Yong-Qing Yang; Yi-Kang Wu


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
98 KB
Volume
23
Category
Article
ISSN
0256-7660

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✦ Synopsis


Abstract

Blastmycinone, a degradation product of the antibiotic antimycin A, was synthesized with a TiCl~4~‐mediated asymmetric aldolization as the key step. Some unexpected yet interesting chemistry was also observed.


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An Efficient Enantioselective Synthesis
✍ Wolfgang Oppolzer; InΓ¨s Rodriguez πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 446 KB

The numbering of 1 corresponds to [2] and is used also for all intermediates; systematic names are given in the Exper. Part. ## ') For the cleavage of cdrboxylates with lithiated alkylsulfones, see [9].