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An Efficient Diamine·Copper Complex-Catalyzed Coupling of Arylboronic Acids with Imidazoles

✍ Scribed by Collman, James P.; Zhong, Min

Book ID
120216714
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
54 KB
Volume
2
Category
Article
ISSN
1523-7060

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An efficient copper-catalyzed coupling of aryl halides with imidazoles
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Copper-catalyzed N-arylation of imidazoles can be accomplished using (CuOTf)2°benzene as a copper source and Cs2CO3 as a base in xylenes at 110-125 °C. Addition of 1,10-phenanthroline (phen) and trans, trans-dibenzylideneacetone (dba) was crucial to the success of the process. The products, N-arylim