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An Efficient [2 + 2 + 1] Synthesis of 2,5-Disubstituted Oxazoles via Gold-Catalyzed Intermolecular Alkyne Oxidation

✍ Scribed by He, Weimin; Li, Chaoqun; Zhang, Liming

Book ID
119976663
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
793 KB
Volume
133
Category
Article
ISSN
0002-7863

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## Abstract The rapid synthesis of 2,4‐ and 2,5‐disubstituted oxazoles __via__ metal‐catalyzed cross‐coupling reactions is reported. The 4‐ or 5‐position of the corresponding 4‐ or 5‐halogenated 2‐butylthiooxazoles was successfully functionalized __via__ Suzuki–Miyaura, Sonogashira and Stille cross