An effective regioselective electrophilic halogenation of tricyclo[5.2.1.02,6]decenyl enaminones
โ Scribed by Namakkal G. Ramesh; Erik H. Heijne; Antonius J.H. Klunder; Binne Zwanenburg
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 260 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
An unexpected tandem regioselective oxidation and cyclization of 5-((S)-2%-hydroxymethylpyrrolidin-1%-yl)-endo-tricyclo[5.2.1.0 2,6 ]deca-4,8-dien-3-ones 7 is reported. The reaction proceeds smoothly to afford novel tetracyclic compounds 8 and 9 in good yield, The structure of 8 was established by s
An efficient enantioselective synthesis of 4-amino-cyclopent-2-ene-l-one 12 from enaminones 8 and and its diastereomer has been accomplished vin a one step 'electron transfer reduction of the enaminone double bond and concomitant removal of an a-methylbenzyl group, followed by a [4 + 21 cycloreversi
Enantioselective Synthesis of 4-Aminocyclopent-2-ene-1-one from Tricyclo[5.2.1.0 2,6 ]decenyl Enaminones. -The enantioselective synthesis of hitherto unknown 4-aminocyclopent-2-en-1-one (VI) involves reaction of enamine (III) with lithium liquid ammonia which not only results in reduction of the en