Reinvestigation relative to the regioselectivity of the aryne cycloaddition. Synthesis of the tricyclo[6.2.0.02,5]-1,5,7-triene-3,10-dione
โ Scribed by Philippe Maurin; Malika Ibrahim-Ouali; Maurice Santelli
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 78 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product. However, it may be expected that
Althoughthemultifarious nature of (CH)ioh.ydrocarbcm chemistryhas engenderedmuch recent interest in these molecules, no attention has yet been paid to the stereoelectronic control which benso fusion could exert on the various bond reorganizations characteristic 1 of the parent systems. In this prel