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An attempted synthesis of tricyclo[8.21,10.01,7.04,10]-1(7),4(10)-dodecadiene

✍ Scribed by John E. McMurry; Rolf Swenson


Book ID
104227211
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
173 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


An Attempted Synthesis of Trioycl0[8.2~*~~.0~*~.0~*~~ I-1(7),4(10)~odecadieaa


πŸ“œ SIMILAR VOLUMES


Formation and rearrangement of tricyclo[
✍ Yutaka Fujise; Takashi Morishima; Kimiyoshi Namiwa; Toshihiro Shiokawa; Yoshimas πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 217 KB

By the action of LDA bicycloC4.4.llundeca-1(10),2,4,8-tetraen-1 l-one was found to undergo transannular cyclization to form a unique tricyclic hydroxydihydroozulene which cleaves a C-C bond by Cn8s+u2251 electrocyclic process and eventually give 4-methylazulene.

Synthesis of the macrocyclic thiocrown e
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The synthesis and characterization of the two macrocyclic s&ides, 1,4,7,lO,l3,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8), are describedstarting from different combmationsof dithiols and dichlorides of differing chain lengths. C&O, is used for the cycl