An attempted synthesis of tricyclo[8.21,10.01,7.04,10]-1(7),4(10)-dodecadiene
β Scribed by John E. McMurry; Rolf Swenson
- Book ID
- 104227211
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 173 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
An Attempted Synthesis of Trioycl0[8.2~*~~.0~*~.0~*~~ I-1(7),4(10)~odecadieaa
π SIMILAR VOLUMES
By the action of LDA bicycloC4.4.llundeca-1(10),2,4,8-tetraen-1 l-one was found to undergo transannular cyclization to form a unique tricyclic hydroxydihydroozulene which cleaves a C-C bond by Cn8s+u2251 electrocyclic process and eventually give 4-methylazulene.
The synthesis and characterization of the two macrocyclic s&ides, 1,4,7,lO,l3,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8), are describedstarting from different combmationsof dithiols and dichlorides of differing chain lengths. C&O, is used for the cycl