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Attempted synthesis of 2,4,8,10-tricyclo[5.4.0.01,6]undecatetraene: bis(norcaradiene)

✍ Scribed by Parker, Richard H.; Jones, W. M.


Book ID
126789500
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
408 KB
Volume
43
Category
Article
ISSN
0022-3263

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The Adamantane Rearrangement of Tricyclo
✍ Kanai L. Ghatak; Camille Ganter πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 German βš– 345 KB πŸ‘ 1 views

Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres