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Synthesis of the macrocyclic thiocrown ethers 1,4,7,10,13,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8)

✍ Scribed by Jilles J.H. Edema; Jan Buter; Richard M. Kellogg

Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 248 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)85071-7

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✦ Synopsis

The synthesis and characterization of the two macrocyclic s&ides, 1,4,7,lO,l3,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8), are describedstarting from different combmationsof dithiols and dichlorides of differing chain lengths. C&O, is used for the cyclizations.

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