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An approach to the bakkanes. A short, stereocontrolled total synthesis of (.+-.)-bakkenolide A

✍ Scribed by Greene, Andrew E.; Depres, Jean Pierre; Coelho, Fernando; Brocksom, Timothy J.


Book ID
127281718
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
448 KB
Volume
50
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Direct approach to the bakkanes: A synth
✍ Fernando Coelho; Jean-Pierre DeprΓ©s; Timothy J. Brocksom; Andrew E. Greene πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 159 KB

A short synthesis of racemic homogynolide-B is described. The key step of the approach, cycloaddition of dichloroketene with the 2,2-dimethyltrimethylene acetal of 2,3-dimethyl-3-cyclohexen-l-one, proceeds with excellent selectivity and in high yield. The bakkanes, a relatively small group of hydri

The First Entry to Complex Bakkanes: A H
✍ Olivier Hamelin; Yanyun Wang; Jean-Pierre DeprΓ©s; Andrew E. Greene πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 98 KB

Dheu-Andries for help with the molecular modeling studies, Mr. F. Bargiggia and Mr. M. Cook for some preliminary experiments, and Prof. M. Kawai (Nagoya Institute of Technology) for samples of natural bakkenolide B and bakkenolide III. Financial support from the Universite Γ‚ Joseph Fourier and the C