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A General Approach Toward Bakkanes: Short Synthesis of (±)-Bakkenolide-A (Fukinanolide) †

✍ Scribed by Reddy, D. Srinivasa


Book ID
120303761
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
54 KB
Volume
6
Category
Article
ISSN
1523-7060

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Direct approach to the bakkanes: A synth
✍ Fernando Coelho; Jean-Pierre Deprés; Timothy J. Brocksom; Andrew E. Greene 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 159 KB

A short synthesis of racemic homogynolide-B is described. The key step of the approach, cycloaddition of dichloroketene with the 2,2-dimethyltrimethylene acetal of 2,3-dimethyl-3-cyclohexen-l-one, proceeds with excellent selectivity and in high yield. The bakkanes, a relatively small group of hydri