The total synthesis of (±)bakkenolide-A
✍ Scribed by D.A. Evans; C.L. Sims
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 197 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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From the bud of Petasites japonicus subsp. giganteusKitam., (local name : Bakke), a plant restricted to the northern part of Japan, two new bitter sesquiterpenoids, bakkenolide -A and bakkenolide-B, have been isolated. The structure of bakkenolide-A is discussed in this communication ; bakkenolide-B
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A Concise Total Synthesis of (±)-Bakkenolide A by Means of an Intramolecular Diels-Alder Reaction. -In addition to bakkenolide A (IV), the epimers (V)-(VII) are obtained. -(BACK, THOMAS G.; PAYNE,