Mixed aminotroponiminate ([ATI] Οͺ ) cyclopentadienyl complexes were prepared using two different synthetic routes. Reaction of [[(iPr) 2 ATI]YCl 2 (THF) 2 ] 2 (1) with KCp\* (Cp\* = C 5 Me 5 ) or Li[C 5 H 3 (SiMe 3 ) 2 ] affords [(iPr) 2 ATI]YCp 2 \* (2a) and [(iPr) 2 ATI]Y[C 5 H 3 (SiMe 3 ) 2 ] 2 (
Aminotroponimines as Ligands for Yttrium and Lanthanide Complexes
β Scribed by Roesky, Peter W.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 467 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Saccharinate complexes of the fourteen trivalent lanthanide cations and Y III were prepared by reaction between the respective lanthanide carbonates and saccharin in aqueous solution. Their crystal structures were determined by single crystal X-ray diffractometry. They represent three different stru
A series of new yttrium(III) double-decker complexes with the same and different phthalocyaninato and porphyrinato ligands has been prepared. The homoleptic complexes Y(P) 2 (P = Pc\*(C 7 H 15 ) 8 , Pc\*(OC 5 H 11 ) 8 ; Pc\* = 2,3,9,10,16,17,23,24-octasubstituted phthalocyaninate) have been synthesi