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Aminocyclopentadienyl Ruthenium Complexes as Racemization Catalysts for Dynamic Kinetic Resolution of Secondary Alcohols at Ambient Temperature

✍ Scribed by Choi, Jun Ho; Choi, Yoon Kyung; Kim, Yu Hwan; Park, Eun Sil; Kim, Eun Jung; Kim, Mahn-Joo; Park, Jaiwook

Book ID
120588961
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
150 KB
Volume
69
Category
Article
ISSN
0022-3263

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Aminocyclopentadienyl Ruthenium Chloride
Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature
✍ Jun Ho Choi; Yu Hwan Kim; Se Hyun Nam; Seung Tae Shin; Mahn-Joo Kim; Jaiwook Par πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 102 KB πŸ‘ 2 views

Dynamic kinetic resolution (DKR) is an attractive method for the complete transformation of a racemic mixture into a single enantiomer. [1] The DKR of secondary alcohols is a prominent example, for which transition-metal-catalyzed racemization is coupled with enzymatic acylation. [2] In particular,