Recently there has been considerable interest in the organometallic chemistry of late transition metals in high oxidation states. Second-and third-row metals in particular were stabilized in high oxidation states by using organic ligand environments. Certain catalytic reactions mediated by these lat
Aminocarbyne Complexes of Chromium in a High Oxidation State—Synthesis, Structure, and Reactivity
✍ Scribed by Prof. Dr. Alexander C. Filippou; Dipl.-Chem. Bernhard Lungwitz; Dipl.-Chem. Klaus M. A. Wanninger; Dr. Eberhardt Herdtweck
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 501 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Recently there has been considerable interest in the organometallic chemistry of late transition metals in high oxidation states. Second-and third-row metals in particular were stabilized in high oxidation states by using organic ligand environments. Certain catalytic reactions mediated by these lat
## 495 [El][BF 4 ] or [El][OSO 2 CF 3 ] (El = H, Me). The dppa backbone of 4 is readily deprotonated by KOSiMe 3 to yield the very stable zwitterionic aminocarbyne complex [(OC) 3 Fe{µ-CN(Me)2,6-xylyl}(µ-Ph 2 PNPPh 2 )Pt(PPh 3 )] 5.