Synthesis, Reactivity, and Molecular Structures of Bis(diphenylphosphanyl)amine- and Bis(diphenylphosphanyl)amide-Bridged Heterobimetallic μ-Isonitrile- and μ-Aminocarbyne Complexes (Fe−Pt)

✍ Scribed by Michael Knorr; Carsten Strohmann

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 499 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199804)1998:4<495::aid-ejic495>3.0.co;2-u

✦ Synopsis

495

[El][BF 4 ] or [El][OSO 2 CF 3 ] (El = H, Me). The dppa backbone of 4 is readily deprotonated by KOSiMe 3 to yield the very stable zwitterionic aminocarbyne complex [(OC) 3 Fe{µ-CN(Me)2,6-xylyl}(µ-Ph 2 PNPPh 2 )Pt(PPh 3 )] 5.