Amine Boranes. I. Kinetics of Acid Hydrolysis of Trimethylamine Borane
β Scribed by Ryschkewitsch, George E.
- Book ID
- 111691552
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 564 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The mechanism of trimethylamine borane (TMAB) hydrolysis in the presence of sulfonate cation exchanger in H+form, H2S03 and trimethylamine deuterosulfate has been established. The hydrolytic reaction is of the first order in TMAB when carried out in the presence of polymeric acid. The rate of TMAB h
Ammonia borane (AB) is a candidate material for on-board hydrogen storage, and hydrolysis is one of the potential processes by which the hydrogen may be released. This paper presents hydrogen generation measurements from the hydrolysis of dilute AB aqueous solutions catalyzed by ruthenium supported